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Palladium(II) acetylacetonate

Palladium(II) acetylacetonate

CAS: 14024-61-4

Molecular Formula: C10H14O4Pd

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Palladium(II) acetylacetonate - Names and Identifiers

Name Palladium(II) acetylacetonate
Synonyms Palladium 2,4-pentanedionate
Palladium(II) acetylacetonate
Bis(acetylaceto)palladium(II)
Bis(acetylacetonato) palladium
Palladium(Ⅱ) 2,4-pentanedionate
Palladium(II)2,4-acetylacetonate
ACETYLACETONE PALLADIUM(II) SALT
Palladium(II) 2,4-pentanedionate
BIS(ACETYLACETONATO)PALLADIUM(II)
Bis(acetylacetonato)palladium(II)
Bis-(2,4-pentanedionato)-palladium
BIS(2,4-PENTANEDIONATO)PALLADIUM(II)
Bis(2,4-pentanedionato)palladium(II)
ACETYLACETONE, PALLADIUM(II) DERIVATIVE
palladium (II) di(4-oxopent-2-en-2-oate)
Bis(2,4-pentanedionato-O,O')palladium(II)
bis(2,4-pentanedionato-o,o')palladium(ii)
palladium(2+) bis[(2Z)-4-oxopent-2-en-2-olate]
Palladium acetylacetonate or Palladium(II)2,4-pentanedionate
Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd
CAS 14024-61-4
EINECS 237-859-8
InChI InChI=1/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-
InChIKey RJJXYEQOOACRKP-LNKPDPKZSA-M

Palladium(II) acetylacetonate - Physico-chemical Properties

Molecular FormulaC10H14O4Pd
Molar Mass304.64
Melting Point190 °C
Boling Point187.6°C at 760 mmHg
Flash Point71.9°C
Water SolubilityINSOLUBLE
Solubility Soluble in benzene and chloroform.
Vapor Presure0Pa at 25℃
AppearanceYellow powder
Specific Gravity1.862
ColorYellow to orange
BRN4136188
Storage ConditionStore below +30°C.
Sensitive4: no reaction with water under neutral conditions
MDLMFCD00000025

Palladium(II) acetylacetonate - Risk and Safety

Risk CodesR36 - Irritating to the eyes
R36/37/38 - Irritating to eyes, respiratory system and skin.
R22 - Harmful if swallowed
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39 - Wear suitable gloves and eye/face protection
UN IDs3181
WGK Germany2
TSCAYes
HS Code28439090

Palladium(II) acetylacetonate - Reference

Reference
Show more
1. [IF=7.79] Xuebi Du et al."Precise design and synthesis of Pd/InOx@CoOx core–shell nanofibers for the highly efficient catalytic combustion of toluene."Nanoscale. 2020 Jun;12(22):12133-12145
2. [IF=6.707] Xuebi Du et al."The synthesis of hollow In2O3 @ Pd-Co3O4 core/shell nanofibers with ultra-thin shell for the low-temperature CO oxidation reaction."Appl Surf Sci. 2020 Mar;505:144471

Palladium(II) acetylacetonate - Reference Information

LogP2.6 at 25℃
NIST chemical information Information provided by: webbook.nist.gov (external link)
EPA chemical information Information provided by: ofmpub.epa.gov (external link)
Use Used for carbonylation, oligomerization and other reactions.
production method 1. suspend 1.299g of palladium dichloride in 2-3mL of hot water, and add 2mL of acetylacetone neutralized with 1: 3KOH. Brown precipitates are slowly generated and then converted to yellow. Continue to add 1mL of neutralized acetylacetone. Collect yellow precipitates and dry at 60~70 ℃. It was recrystallized in benzene to give yellow needle-like crystals of Pd(acac)2 in 76% yields. 2. Take 4mL of NaOH solution with a concentration of 5mol/L, and add a mixed solution consisting of 2.5mL of acetylacetone and 10mL of Na2[PdCl4] solution with a concentration of 0.5mol/L under stirring. The reaction produces a yellow precipitate, which is filtered and sequentially washed with a small amount of water, methanol and ether. Dissolve the yellow powder in dichloromethane and filter to remove a small amount of insoluble matter. The filtrate was volatilized at room temperature to remove the solvent, and 1.37g orange-red crystals were obtained with 90% yield. The yield of this method is better than that of method 1 using PdCl2 as raw material.
Last Update:2024-04-10 22:29:15
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View History
Palladium(II) acetylacetonate
1H-Pyrazolo[3,4-c]pyridine-3-carboxylic acid, 6-(4-aminophenyl)-4,5,6,7-tetrahydro-1-(4-methoxyphenyl)-7-oxo-, ethyl ester
ASISCHEM V69547
甲基泼尼松龙乙丙酸酯
1-[2-fluoro-6-(2-methoxyphenoxy)phenyl]ethan-1-amine
2-METHYLPROPANE-2-D
5-氯-2-氨基烟酸
1-氨基-4-溴-2-甲基-9,10-二氢蒽-9,10-二酮
16,17-二癸氧基蒽酮紫(红外染料)
3-NITROPYRAZOLO[1,5-A]PYRIMIDINE
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